I looked around but didn't not see anywhere to add new administrators in the admin panel.
Is this possible?
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"Security" not a very intuitive tab name. Users might be more appropriate.
Changing the name from 'Security' to 'Administrator' you mean? if so, put the following code in mysite/_config.php file
LeftAndMain::$removed_menu_items = array('security');
LeftAndMain::$extra_menu_items = array(_t('LeftAndMain.ADMINISTRATOR',"Administrator",PR_HIGH,'Menu title') => array("security", "admin/security/", "SecurityAdmin"));